dc.contributor.authorAllieta, Mattia
dc.contributor.authorScavini, Marco
dc.contributor.authorSpalek, Leszek J.
dc.contributor.authorScagnoli, Valerio
dc.contributor.authorWalker, Helen C.
dc.contributor.authorPanagopoulos, Christos
dc.contributor.authorSaxena, Siddharth S.
dc.contributor.authorKatsufuji, Takuro
dc.contributor.authorMazzoli, Claudio
dc.date.accessioned2013-02-25T03:25:59Z
dc.date.available2013-02-25T03:25:59Z
dc.date.copyright2012en_US
dc.date.issued2012
dc.identifier.citationAllieta, M., Scavini, M., Spalek, L. J., Scagnoli, V., Walker, H. C., Panagopoulos, C., et al. (2012). Role of intrinsic disorder in the structural phase transition of magnetoelectric EuTiO3. Physical Review B, 85(18), 184107-.en_US
dc.identifier.urihttp://hdl.handle.net/10220/9230
dc.description.abstractUp to now, the crystallographic structure of the magnetoelectric perovskite EuTiO3 has been considered to remain cubic down to low temperature. Here we present high-resolution synchrotron x-ray powder-diffraction data showing the existence of a structural phase transition, from cubic Pm-3m to tetragonal I4/mcm, involving TiO6 octahedra tilting, in analogy to the case of SrTiO3. The temperature evolution of the tilting angle and of the full width at half maximum of the (200) cubic reflection family indicate a critical temperature Tc = 235 K. This critical temperature is well below the recent anomaly reported by specific-heat measurement at TA ∼ 282 K. By performing atomic pair distribution function analysis on diffraction data, we provide evidence of a mismatch between the local (short-range) and the average crystallographic structures in this material. Below the estimated Tc, the average model symmetry is fully compatible with the local environment distortion, but the former is characterized by a reduced value of the tilting angle compared to the latter. At T = 240 K, data show the presence of local octahedra tilting identical to the low-temperature one, while the average crystallographic structure remains cubic. On this basis, we propose that intrinsic lattice disorder is of fundamental importance in the understanding of EuTiO3 properties.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesPhysical review Ben_US
dc.rights© 2012 American Physical Society. This paper was published in Physical Review B and is made available as an electronic reprint (preprint) with permission of American Physical Society. The paper can be found at the following official DOI: [http://dx.doi.org/10.1103/PhysRevB.85.184107]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.en_US
dc.subjectDRNTU::Science::Chemistry::Crystallography
dc.titleRole of intrinsic disorder in the structural phase transition of magnetoelectric EuTiO3en_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1103/PhysRevB.85.184107
dc.description.versionPublished versionen_US


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