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Title: Access to oxoquinoline heterocycles by N-heterocyclic carbene catalyzed ester activation for selective reaction with an enone
Authors: Fu, Zhenqian
Jiang, Ke
Zhu, Tingshun
Torres, Jaume
Chi, Robin Yonggui
Keywords: DRNTU::Science::Chemistry::Inorganic chemistry::Cyclic compounds
Issue Date: 2014
Source: Fu, Z., Jiang, K., Zhu, T., Torres, J., & Chi, Y. R. (2014). Access to Oxoquinoline Heterocycles by N-Heterocyclic Carbene Catalyzed Ester Activation for Selective Reaction with an Enone. Angewandte Chemie International Edition, 53(25), 6506–6510.
Series/Report no.: Angewandte chemie international edition
Abstract: Organocatalytic ester activation is developed for a highly selective cascade reaction between saturated esters and amino enones. The reaction involves activation of the β-carbon atom of the ester as a key step. This method allows a single-step access to multicyclic oxoquinoline-type heterocycles with high enantiomeric ratios.
ISSN: 1433-7851
DOI: 10.1002/anie.201402620
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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