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|Title:||Experimentally validated raman Monte Carlo simulation for a cuboid object to obtain raman spectroscopic signatures for hidden material||Authors:||Periyasamy, Vijitha
|Keywords:||DRNTU::Science::Medicine::Biomedical engineering||Issue Date:||2015||Source:||Periyasamy, V., Sil, S., Dhal, G., Ariese, F., Umapathy, S., & Pramanik, M. (2015). Experimentally validated raman Monte Carlo simulation for a cuboid object to obtain raman spectroscopic signatures for hidden material. Journal of raman spectroscopy, 46(7), 669-676.||Series/Report no.:||Journal of raman spectroscopy||Abstract:||In conventional Raman spectroscopic measurements of liquids or surfaces the preferred geometry for detection of the Raman signal is the backscattering (or reflection) mode. For nontransparent layered materials, sub-surface Raman signals have been retrieved using spatially offset Raman spectroscopy (SORS), usually with light collection in the same plane as the point of excitation. However, as a result of multiple scattering in a turbid medium, Raman photons will be emitted in all directions. In this study, Monte Carlo simulations for a three-dimensional layered sample with finite geometry have been performed to confirm the detectability of Raman signals at all angles and at all sides of the object. We considered a non-transparent cuboid container (high density polyethylene) with explosive material (ammonium nitrate) inside. The simulation results were validated with experimental Raman intensities. Monte Carlo simulation results reveal that the ratio of sub-surface to surface signals improves at geometries other than backscattering. In addition, we demonstrate through simulations the effects of the absorption and scattering coefficients of the layers, and that of the diameter of the excitation beam. The advantage of collecting light from all possible 4π angles, over other collection modes is that this technique is not geometry specific and molecular identification of layers underneath nontransparent surfaces can be obtained with minimal interference from the surface layer. To what extent all sides of the object will contribute to the total signal will depend on the absorption and scattering coefficients and the physical dimensions.||URI:||https://hdl.handle.net/10356/100064
|ISSN:||0377-0486||DOI:||10.1002/jrs.4709||Rights:||© 2015 John Wiley & Sons Ltd. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Raman Spectroscopy, John Wiley & Sons Ltd. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1002/jrs.4709].||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||SCBE Journal Articles|
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