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Title: Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
Authors: Wu, Xiaojin
Lu, Yunpeng
Hirao, Hajime
Zhou, Jianrong Steve
Keywords: DRNTU::Science::Chemistry
Issue Date: 2013
Source: Wu, X., Lu, Y., Hirao, H., & Zhou, J. S. (2013). Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins. Chemistry - A European journal, 19(19), 6014-6020.
Series/Report no.: Chemistry - a European journal
Abstract: In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium–hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions.
ISSN: 0947-6539
DOI: 10.1002/chem.201204427
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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