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https://hdl.handle.net/10356/100998| Title: | Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride | Authors: | Guo, Jia-Yi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai |
Issue Date: | 2012 | Source: | Guo, J.-Y., Li, Y., Ganguly, R., & So, C.-K. (2012). Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex toward Isocyanates and Rhodium(I) Chloride. Organometallics, 31(10), 3888–3893. | Series/Report no.: | Organometallics | Abstract: | The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2═NSiMe3)(PPh2═S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography. | URI: | https://hdl.handle.net/10356/100998 http://hdl.handle.net/10220/13701 |
DOI: | 10.1021/om300062n | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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