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Title: Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
Authors: Guo, Jia-Yi
Li, Yongxin
Ganguly, Rakesh
So, Cheuk-Wai
Issue Date: 2012
Source: Guo, J.-Y., Li, Y., Ganguly, R., & So, C.-K. (2012). Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex toward Isocyanates and Rhodium(I) Chloride. Organometallics, 31(10), 3888–3893.
Series/Report no.: Organometallics
Abstract: The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2═NSiMe3)(PPh2═S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography.
DOI: 10.1021/om300062n
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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