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https://hdl.handle.net/10356/101028| Title: | Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines | Authors: | Kumaran, Elumalai Leong, Weng Kee |
Issue Date: | 2012 | Source: | Kumaran, E., & Leong, W. K. (2012). Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines. Organometallics, 31(3), 1068–1072. | Series/Report no.: | Organometallics | Abstract: | The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies. | URI: | https://hdl.handle.net/10356/101028 http://hdl.handle.net/10220/13695 |
DOI: | 10.1021/om201134j | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om201134j]. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Rhodium(III) Catalysed Hydroamination of Aromatic Terminal Alkynes.pdf | 204.38 kB | Adobe PDF |  View/Open |
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