Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/101028
Title: Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines
Authors: Kumaran, Elumalai
Leong, Weng Kee
Issue Date: 2012
Source: Kumaran, E., & Leong, W. K. (2012). Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines. Organometallics, 31(3), 1068–1072.
Series/Report no.: Organometallics
Abstract: The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.
URI: https://hdl.handle.net/10356/101028
http://hdl.handle.net/10220/13695
DOI: 10.1021/om201134j
Rights: © 2012 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om201134j].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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