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|Title:||In situ synthesized heteropoly acid/polyaniline/graphene nanocomposites to simultaneously boost both double layer- and pseudo-capacitance for supercapacitors||Authors:||Cui, Zhiming
Guo, Chun Xian
Li, Chang Ming
|Issue Date:||2012||Source:||Cui, Z., Guo, C. X., Yuan, W., Li, C. M. (2012). In situ synthesized heteropoly acid/polyaniline/graphene nanocomposites to simultaneously boost both double layer- and pseudo-capacitance for supercapacitors. Physical Chemistry Chemical Physics, 14(37), 12823-12828.||Series/Report no.:||Physical chemistry chemical physics||Abstract:||It is challenging to simultaneously increase double layer- and pseudo-capacitance for supercapacitors. Phosphomolybdic acid/polyaniline/graphene nanocomposites (PMo12–PANI/GS) were prepared by using PMo12 as a bifunctional reagent for not only well dispersing graphene for high electrochemical double layer capacitance but also in situ chemically polymerizing aniline for high pseudocapacitance, resulting in a specific capacitance of 587 F g−1, which is [similar]1.5 and 6 times higher than that of PANI/GS (392 F g−1) and GS (103 F g−1), respectively. The nanocomposites also exhibit good reversibility and stability. Other kinds of heteropolyacids such as molybdovanadophosphoric acids (PMo12−xVx, x = 1, 2 and 3) were also used to prepare PMo12−xVx–PANI/GS nanocomposites, also showing enhanced double layer- and pseudo-capacitance. This further proves the proposed concept to simultaneously boost both double layer- and pseudo-capacitance and demonstrates that it could be a universal approach to significantly improve the capacitance for supercapacitors.||URI:||https://hdl.handle.net/10356/101091
|DOI:||10.1039/C2CP42022H||Rights:||© 2012 The Owner Societies.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SCBE Journal Articles|
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