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Title: Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines
Authors: Qi, Xinxin
Dai, Lu
Park, Cheol-Min
Issue Date: 2012
Source: Qi, X., Dai, L., Park, C.-M. (2012). Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines. Chemical Communications, 48(91), 11244-11246.
Series/Report no.: Chemical communications
Abstract: Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N–O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5–10 minutes in good to excellent yields.
DOI: 10.1039/c2cc36009h
Rights: © 2012 The Royal Society of Chemistry.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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