Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/101380
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dc.contributor.authorKumaran, Elumalaien
dc.contributor.authorLeong, Weng Keeen
dc.date.accessioned2014-01-20T02:34:47Zen
dc.date.accessioned2019-12-06T20:37:32Z-
dc.date.available2014-01-20T02:34:47Zen
dc.date.available2019-12-06T20:37:32Z-
dc.date.copyright2012en
dc.date.issued2012en
dc.identifier.citationKumaran, E., & Leong, W. K. (2012). The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes. Organometallics, 31(13), 4849-4853.en
dc.identifier.urihttps://hdl.handle.net/10356/101380-
dc.description.abstractThe reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent5p.en
dc.language.isoenen
dc.relation.ispartofseriesOrganometallicsen
dc.rights© 2012 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om300387q].en
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compoundsen
dc.titleThe reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1021/om300387qen
dc.description.versionAccepted versionen
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