Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/101388
Title: Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
Authors: Rakesh, Ganguly
Wang, Xiao-Jun
Li, Pei-Zhou
Liu, Lei
Zhang, Quan
Borah, Parijat
Wong, Jinye Daniel
Chan, Xiu Xiang
Li, Yongxin
Zhao, Yanli
Issue Date: 2012
Source: Wang, X.-J., Li, P.-Z., Liu, L., Zhang, Q., Borah, P., Wong, J. D., et al. (2012). Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework. Chemical Communications, 48(83), 10268-10288.
Series/Report no.: Chemical communications
Abstract: Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N2 and CH4.
URI: https://hdl.handle.net/10356/101388
http://hdl.handle.net/10220/11111
DOI: 10.1039/c2cc34921c
Rights: © 2012 The Royal Society of Chemistry.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.