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Title: Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
Authors: Kumaran, Elumalai
How, Kai Tong Sonia
Ganguly, Rakesh
Li, Yongxin
Leong, Weng Kee
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2013
Source: Kumaran, E., How, K. T. S., Ganguly, R., Li, Y., & Leong, W. K. (2013). Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines. Organometallics, 32(15), 4149-4152.
Series/Report no.: Organometallics
Abstract: The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies.
DOI: 10.1021/om400326c
Rights: © 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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