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dc.contributor.authorKumaran, Elumalaien
dc.contributor.authorHow, Kai Tong Soniaen
dc.contributor.authorGanguly, Rakeshen
dc.contributor.authorLi, Yongxinen
dc.contributor.authorLeong, Weng Keeen
dc.identifier.citationKumaran, E., How, K. T. S., Ganguly, R., Li, Y., & Leong, W. K. (2013). Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines. Organometallics, 32(15), 4149-4152.en
dc.description.abstractThe reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.rights© 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].en
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compoundsen
dc.titleSynthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridinesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.description.versionAccepted versionen
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