Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/101747
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dc.contributor.authorLi, Xiukaien
dc.contributor.authorWu, Dien
dc.contributor.authorLu, Tingen
dc.contributor.authorYi, Guangshunen
dc.contributor.authorSu, Haibinen
dc.contributor.authorZhang, Yugenen
dc.date.accessioned2014-06-10T08:38:34Zen
dc.date.accessioned2019-12-06T20:43:52Z-
dc.date.available2014-06-10T08:38:34Zen
dc.date.available2019-12-06T20:43:52Z-
dc.date.copyright2014en
dc.date.issued2014en
dc.identifier.citationLi, X., Wu, D., Lu, T., Yi, G., Su, H., & Zhang, Y. (2014). Highly Efficient Chemical Process To Convert Mucic Acid into Adipic Acid and DFT Studies of the Mechanism of the Rhenium-Catalyzed Deoxydehydration. Angewandte Chemie, 126(16), 4284-4288.en
dc.identifier.issn0044-8249en
dc.identifier.urihttps://hdl.handle.net/10356/101747-
dc.description.abstractThe production of bulk chemicals and fuels from renewable bio-based feedstocks is of significant importance for the sustainability of human society. Adipic acid, as one of the most-demanded drop-in chemicals from a bioresource, is used primarily for the large-volume production of nylon-6,6 polyamide. It is highly desirable to develop sustainable and environmentally friendly processes for the production of adipic acid from renewable feedstocks. However, currently there is no suitable bio-adipic acid synthesis process. Demonstrated herein is the highly efficient synthetic protocol for the conversion of mucic acid into adipic acid through the oxorhenium-complex-catalyzed deoxydehydration (DODH) reaction and subsequent Pt/C-catalyzed transfer hydrogenation. Quantitative yields (99 %) were achieved for the conversion of mucic acid into muconic acid and adipic acid either in separate sequences or in a one-step process.en
dc.description.sponsorshipASTAR (Agency for Sci., Tech. and Research, S’pore)en
dc.language.isoenen
dc.relation.ispartofseriesAngewandte chemieen
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistry::Organic chemistryen
dc.titleHighly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydrationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science & Engineeringen
dc.identifier.doi10.1002/ange.201310991en
item.fulltextNo Fulltext-
item.grantfulltextnone-
Appears in Collections:MSE Journal Articles

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