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Title: Synthesis of cross-linked comb-type polysiloxane for polymer electrolyte membranes
Authors: Abadie, Marc J. M.
Mukbaniani, Omar
Aneli, Jimsher
Tatrishvili, Tamara
Markarashvili, Eliza
Chigvinadze, Maia
Keywords: DRNTU::Engineering::Materials
Issue Date: 2012
Source: Mukbaniani, O., Aneli, J., Tatrishvili, T., Markarashvili, E., Chigvinadze, M., & Abadie, M. J. M. (2012). Synthesis of cross-linked comb-type polysiloxane for polymer electrolyte membranes. e-Polymers, 12(1), 1-14.
Series/Report no.: e-Polymers
Abstract: Hydrosilylation reaction of with allyl acetoacetate and vinyltriethoxysilane at 1:3:1 ratio of initial compounds in the presence of Karstedt’s catalyst (Pt2[(VinSiMe2)2O]3), platinum hydrochloric acid (0.1 M solution in THF) and platinum on the carbon have been studied and D4R,R’ type methylorganocyclotetrasiloxane has been obtained. Ring-opening co-polymerization reactions of methylorganocyclotetrasiloxane and hexamethyldisiloxane, in the presence of catalytic amount of powder-like potassium hydroxide, have been carried out and linear methylsiloxane oligomer with regular arrangement of propyl acetoacetate and triethoxysilane groups in the side chain has been obtained. The synthesized methylorganocyclotetrasiloxane and oligomers were studied by FTIR, 1H, 13C, 29Si NMR spectroscopy. Comb-type oligomers were characterized by gel-permeation chromatography, wide- angle X-ray and differential scanning calorimetric methods. Via sol-gel processes of doped with lithium trifluoromethylsulfonate (triflate) or lithium bis- (trifluoromethylsulfonyl)imide oligomer systems solid polymer electrolyte membranes have been obtained. The dependence of ionic conductivity as a function of temperature and salt concentration has been studied. The electrical conductivity of these materials at room temperature belongs to the range of 7x10-8 to 4x10-6 S cm-1 and depends on the structures of grafted anion receptors and the polymer backbones.
ISSN: 1618-7229
Rights: © 2012 De Gruyter. This paper was published in e-Polymers and is made available as an electronic reprint (preprint) with permission of De Gruyter. The paper can be found at the following official URL:  One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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