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https://hdl.handle.net/10356/102577| Title: | Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation : formal synthesis of aspergillide A | Authors: | Xiang, Shaohua Cai, Shuting Liu, Xue-Wei Zeng, Jing Ma, Jimei |
Keywords: | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds | Issue Date: | 2013 | Source: | Zeng, J., Ma, J., Xiang, S., Cai, S., & Liu, X.-W. (2013). Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation : formal synthesis of aspergillide A. Angewandte Chemie International Edition, 52(19), 5134-5137. | Series/Report no.: | Angewandte chemie international edition | Abstract: | Mild and sweet: The title reaction proceeds under mild conditions with high regio- and diastereoselectivity (see scheme, PG=protecting group, DiPPF=1,1′-bis(diisopropylphosphino)ferrocene). This reaction is suitable for a wide range of glycal-derived γ-ketone esters and affords C-glycosides with exclusive β-selectivity. The method was further applied to a concise formal synthesis of aspergillide A. | URI: | https://hdl.handle.net/10356/102577 http://hdl.handle.net/10220/19122 |
ISSN: | 1433-7851 | DOI: | 10.1002/anie.201210266 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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