Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/102582
Title: Radical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates : highly diastereoselective synthesis of trans-diamines from cycloalkenes
Authors: Zhu, Ming-Kui
Chen, Yu-Chen
Loh, Teck-Peng
Keywords: DRNTU::Science::Chemistry::Organic chemistry
Issue Date: 2013
Source: Zhu, M.-K., Chen, Y.-C., & Loh, T.-P. (2013). Radical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates : highly diastereoselective synthesis of trans-diamines from cycloalkenes. Chemistry - A European Journal, 19(17), 5250-5254.
Series/Report no.: Chemistry - a European journal
Abstract: Metal-free synthesis: Diamination of alkenes by using phenylhydrazine and azodicarboxylates could be achieved in a one-pot manner under very mild conditions (see scheme; Boc=tert-butoxycarbonyl). This process works with the assistance of acetic acid by means of a radical mechanism and displays a high trans selectivity when cycloalkene substrates were used in the reaction.
URI: https://hdl.handle.net/10356/102582
http://hdl.handle.net/10220/19226
ISSN: 0947-6539
DOI: 10.1002/chem.201203832
Rights: © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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