Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/102922
Title: CH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexes
Authors: Xu, Xiangya
Pooi, Benjamin
Hirao, Hajime
Hong, Soon Hyeok
Keywords: DRNTU::Science::Chemistry
Issue Date: 2014
Source: Xu, X., Pooi, B., Hirao, H., & Hong, S. H. (2014). CH-π and CF-π Interactions Lead to Structural Changes of N-Heterocyclic Carbene Palladium Complexes. Angewandte Chemie International Edition, 53(5), 1283-1287.
Series/Report no.: Angewandte chemie international edition
Abstract: The role of CH–π and CF–π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH–π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF–π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1-pentafluorophenylimidazol-2-ylidene) palladium(II).
URI: https://hdl.handle.net/10356/102922
http://hdl.handle.net/10220/19149
ISSN: 1433-7851
DOI: 10.1002/anie.201309371
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

SCOPUSTM   
Citations 10

30
Updated on Jan 29, 2023

Web of ScienceTM
Citations 10

29
Updated on Jan 30, 2023

Page view(s)

333
Updated on Feb 1, 2023

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.