Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/102922
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dc.contributor.authorXu, Xiangyaen
dc.contributor.authorPooi, Benjaminen
dc.contributor.authorHirao, Hajimeen
dc.contributor.authorHong, Soon Hyeoken
dc.date.accessioned2014-04-07T04:52:27Zen
dc.date.accessioned2019-12-06T21:02:21Z-
dc.date.available2014-04-07T04:52:27Zen
dc.date.available2019-12-06T21:02:21Z-
dc.date.copyright2014en
dc.date.issued2014en
dc.identifier.citationXu, X., Pooi, B., Hirao, H., & Hong, S. H. (2014). CH-π and CF-π Interactions Lead to Structural Changes of N-Heterocyclic Carbene Palladium Complexes. Angewandte Chemie International Edition, 53(5), 1283-1287.en
dc.identifier.issn1433-7851en
dc.identifier.urihttps://hdl.handle.net/10356/102922-
dc.description.abstractThe role of CH–π and CF–π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH–π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF–π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1-pentafluorophenylimidazol-2-ylidene) palladium(II).en
dc.language.isoenen
dc.relation.ispartofseriesAngewandte chemie international editionen
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistryen
dc.titleCH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/anie.201309371en
item.grantfulltextnone-
item.fulltextNo Fulltext-
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