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Title: Surfactant-thermal method to synthesize a novel two-dimensional oxochalcogenide
Authors: Gao, Junkuo
Tay, Qiuling
Li, Pei-Zhou
Xiong, Wei-Wei
Zhao, Yanli
Chen, Zhong
Zhang, Qichun
Keywords: DRNTU::Engineering::Materials::Photonics and optoelectronics materials
Issue Date: 2014
Source: Gao, J., Tay, Q., Li, P.-Z., Xiong, W.-W., Zhao, Y., Chen, Z., et al. (2014). Surfactant-Thermal Method to Synthesize a Novel Two-Dimensional Oxochalcogenide. Chemistry - An Asian Journal, 9(1), 131-134.
Series/Report no.: Chemistry - an Asian journal
Abstract: A new two-dimensional (2D) oxosulfide, (N2H4)2Mn3Sb4S8(μ3-OH)2 (1), has been successfully synthesized under surfactant–thermal conditions with hexadecyltributylphosphonium bromide as the surfactant. Compound 1 has a layered structure and contains a novel [Mn3(μ3-OH)2]n chain along the b-axis. The photocatalytic activity for compound 1 has been demonstrated under visible-light irradiation and continuous H2 evolution was observed. Our results indicate that surfactant–thermal synthesis could be a promising method for growing novel crystalline oxochalcogenides with interesting structures and properties.
ISSN: 1861-4728
DOI: 10.1002/asia.201301023
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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