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https://hdl.handle.net/10356/103050| Title: | Halogen-bonding-induced hydrogen transfer to C═N bond with hantzsch ester | Authors: | He, Wei Ge, Yi-Cen Tan, Choon-Hong |
Keywords: | DRNTU::Science::Chemistry::Organic chemistry | Issue Date: | 2014 | Source: | He, W., Ge, Y.-C., & Tan, C.-H. (2014). Halogen-bonding-induced hydrogen transfer to C═N bond with hantzsch ester. Organic letters, 16(12), 3244-3247. | Series/Report no.: | Organic letters | Abstract: | Several bidentate dihydroimidazolines were prepared and investigated as catalysts for hydrogen transfer reduction of C═N bond with Hantzsch ester. Highly efficient reactions were observed for quinolines and imines with low catalyst loading of 2 mol %. The presence of halogen bonding was elucidated using NMR studies and isothermal calorimeric titrations. Binding constants of the XB donors were also measured using isothermal calorimeric titrations (ITC). | URI: | https://hdl.handle.net/10356/103050 http://hdl.handle.net/10220/24358 |
DOI: | 10.1021/ol501259q | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/ol501259q]. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Halogen Bonding Induced Hydrogen Transfer to C | 706.64 kB | Unknown | View/Open |
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