Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103106
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dc.contributor.authorTan, Boon-Hongen
dc.contributor.authorYoshikai, Naohikoen
dc.date.accessioned2014-12-09T02:41:29Zen
dc.date.accessioned2019-12-06T21:05:44Z-
dc.date.available2014-12-09T02:41:29Zen
dc.date.available2019-12-06T21:05:44Z-
dc.date.copyright2014en
dc.date.issued2014en
dc.identifier.citationTan, B.-H., & Yoshikai, N. (2014). Cobalt-catalyzed addition of arylzinc reagents to norbornene derivatives through 1,4-cobalt mgration. Organic letters, 16(12), 3392-3395.en
dc.identifier.urihttps://hdl.handle.net/10356/103106-
dc.description.abstractA cobalt–diphosphine catalyst promotes the addition of an arylzinc reagent to a norbornene derivative to afford o-(2-exo-norbornyl)arylzinc species. This “migratory arylzincation” reaction is considered to involve insertion of norbornene into an arylcobalt species, alkyl-to-aryl 1,4-cobalt migration, and transmetalation between the resulting o-(2-exo-norbornyl)arylcobalt species and the arylzinc reagent. The o-(2-exo-norbornyl)arylzinc species can be intercepted by common organic electrophiles under copper or palladium catalysis.en
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en
dc.format.extent6 p.en
dc.language.isoenen
dc.relation.ispartofseriesOrganic lettersen
dc.rights© 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/ol501449j].en
dc.subjectDRNTU::Science::Chemistryen
dc.titleCobalt-catalyzed addition of arylzinc reagents to norbornene derivatives through 1,4-cobalt mgrationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1021/ol501449jen
dc.description.versionAccepted versionen
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