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Title: Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
Authors: Li, Ying-Zhou
Ganguly, Rakesh
Leong, Weng Kee
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2014
Source: Li, Y.-Z., Ganguly, R., & Leong, W. K. (2014). Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate. Organometallics, 33(3), 823-828.
Series/Report no.: Organometallics
Abstract: The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxidative addition reaction was trapped as a W(CO)5 adduct.
DOI: 10.1021/om401206d
Rights: © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI:].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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