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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Li, Ying-Zhou | en |
dc.contributor.author | Ganguly, Rakesh | en |
dc.contributor.author | Leong, Weng Kee | en |
dc.date.accessioned | 2014-12-09T06:07:15Z | en |
dc.date.accessioned | 2019-12-06T21:07:52Z | - |
dc.date.available | 2014-12-09T06:07:15Z | en |
dc.date.available | 2019-12-06T21:07:52Z | - |
dc.date.copyright | 2014 | en |
dc.date.issued | 2014 | en |
dc.identifier.citation | Li, Y.-Z., Ganguly, R., & Leong, W. K. (2014). Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate. Organometallics, 33(3), 823-828. | en |
dc.identifier.uri | https://hdl.handle.net/10356/103225 | - |
dc.description.abstract | The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxidative addition reaction was trapped as a W(CO)5 adduct. | en |
dc.format.extent | 6 p. | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Organometallics | en |
dc.rights | © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/om401206d]. | en |
dc.subject | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds | en |
dc.title | Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate | en |
dc.type | Journal Article | en |
dc.contributor.school | School of Physical and Mathematical Sciences | en |
dc.identifier.doi | 10.1021/om401206d | en |
dc.description.version | Accepted version | en |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
Appears in Collections: | SPMS Journal Articles |
Files in This Item:
File | Description | Size | Format | |
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Oxidative addition across Sb-H and Sb-Sb bonds by an osmium carbonyl cluster.pdf | Main article | 3.16 MB | Adobe PDF | View/Open |
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