Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103240
Title: Hydrothermal assembly of two new 3D zinc(II) pcu nets : coordination chemistry, crystal structures, and fluorescence properties
Authors: Zhu, Xiaofei
Yang, Yu
Jiang, Ning
Li, Bo
Zhou, Defeng
Fu, Hai
Wang, Ning
Keywords: DRNTU::Engineering::Materials::Compositional materials science
Issue Date: 2015
Source: Zhu, X., Yang, Y., Jiang, N., Li, B., Zhou, D., Fu, H., et al. (2015). Hydrothermal assembly of two new 3D zinc(II) pcu nets : coordination chemistry, crystal structures, and fluorescence properties. Zeitschrift für anorganische und allgemeine chemie, 641(3-4), 699-703.
Series/Report no.: Zeitschrift für anorganische und allgemeine chemie
Abstract: Self-assembly of zinc(II) coordination polymers have attracted intense interests due to their intriguing frameworks and fluorescence properties. Two new 3D ZnII coordination polymers with pcu networks, formulated by [Zn2L1L2(mbtz)]·H2O (1) and [Zn4L12L22(btp)2]·7H2O (2) [H2L1 = 2,5-dibenzoylterephthalic acid, H2L2 = 4,6-dibenzoylisophthalic acid, mbtz = 1,3-bis(1,2,4-triazol-1-ylmethyl)benzene, and btp = 1,3-bis(1,2,4-triazol-1-yl)propane], were synthesized under normal hydrothermal conditions. Single-crystal X-ray diffraction analyses revealed that both of the two compounds exhibited interesting 3D pcu frameworks, and showed shifted fluorescent emissions arising from the coordination chemistry between ZnII and the N-donor ligands.
URI: https://hdl.handle.net/10356/103240
http://hdl.handle.net/10220/25771
ISSN: 0044-2313
DOI: 10.1002/zaac.201400459
Rights: © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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