Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103605
Title: Palladacycle catalyzed asymmetric P-H addition of diarylphosphines to N-enoyl phthalimides
Authors: Chew, Renta Jonathan
Lu, Yunpeng
Jia, Yu-Xiang
Li, Bin-Bin
Wong, Esther Hui Yen
Goh, Rosanne
Li, Yongxin
Huang, Yinhua
Pullarkat, Sumod Appukuttan
Leung, Pak-Hing
Keywords: DRNTU::Science::Chemistry::Organic chemistry
Issue Date: 2014
Source: Chew, R. J., Lu, Y., Jia, Y.-X., Li, B.-B., Wong, E. H. Y., Goh, R., et al. (2014). Palladacycle catalyzed asymmetric P-H addition of diarylphosphines to N-enoyl phthalimides. Chemistry - A European journal, 20(44), 14514-14517.
Series/Report no.: Chemistry - A European journal
Abstract: The first asymmetric phospha-Michael addition of diarylphosphines to N-enoyl phthalimides has been developed in the presence of a chiral palladacycle catalyst. A library of free chiral tertiary phosphine adducts were directly obtained with excellent yields and enantioselectivities. Products can be subsequently functionalized to afford β-phosphinoamides, the direct preparation of which from cinnamides has been notoriously challenging.
URI: https://hdl.handle.net/10356/103605
http://hdl.handle.net/10220/24566
ISSN: 0947-6539
DOI: 10.1002/chem.201403885
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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