Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103735
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dc.contributor.authorWong, Jonathanen
dc.contributor.authorGan, Kennarden
dc.contributor.authorChen, Houguang Jeremyen
dc.contributor.authorPullarkat, Sumod A.en
dc.date.accessioned2014-12-30T01:47:27Zen
dc.date.accessioned2019-12-06T21:19:07Z-
dc.date.available2014-12-30T01:47:27Zen
dc.date.available2019-12-06T21:19:07Z-
dc.date.copyright2014en
dc.date.issued2014en
dc.identifier.citationWong, J., Gan, K., Chen, H. J., & Pullarkat, S. A. (2014). Evaluation of palladacycles as a non-rhodium based alternative for the asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated enones. Advanced synthesis & catalysis, 356(16), 3391-3400.en
dc.identifier.issn1615-4150en
dc.identifier.urihttps://hdl.handle.net/10356/103735-
dc.description.abstractThe asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds is an extremely versatile and widely used organic transformation. While the rhodium(I)-catalysed reaction has been thoroughly explored, the asymmetric palladium-catalysed protocol is far less developed and understood, particularly with acyclic enones as substrates. Herein, we report the systematic evaluation of a series of metallacycles for this reaction and the conjugate addition of arylboronic acids to a wide range of α,β-unsaturated enones, catalysed by an easily accessible and robust chiral phosphapalladacycle in high yields and enantioselectivities.en
dc.language.isoenen
dc.relation.ispartofseriesAdvanced synthesis & catalysisen
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistry::Inorganic chemistry::Synthesisen
dc.titleEvaluation of palladacycles as a non-rhodium based alternative for the asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated enonesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/adsc.201400473en
item.grantfulltextnone-
item.fulltextNo Fulltext-
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