Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103771
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dc.contributor.authorXu, Wengangen
dc.contributor.authorPaira, Rupankaren
dc.contributor.authorYoshikai, Naohikoen
dc.date.accessioned2015-10-12T03:27:19Zen
dc.date.accessioned2019-12-06T21:19:53Z-
dc.date.available2015-10-12T03:27:19Zen
dc.date.available2019-12-06T21:19:53Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationXu, W., Paira, R., & Yoshikai, N. (2015). Ortho-C–H Benzylation of Aryl Imines with Benzyl Phosphates under Cobalt–Pyphos Catalysis. Organic Letters, 17(17), 4192-4195.en
dc.identifier.issn1523-7060en
dc.identifier.urihttps://hdl.handle.net/10356/103771-
dc.identifier.urihttp://hdl.handle.net/10220/38789en
dc.description.abstractOrtho-C–H benzylation of aryl ketimines with benzyl phosphates is achieved with the aid of a catalytic system consisting of a cobalt(II) salt, a phosphine/pyridine bidentate ligand, and a Grignard reagent under room-temperature conditions, affording a variety of diarylmethanes bearing o-acetyl or -acyl groups in moderate to good yields. Owing to the versatility of the o-acetyl group, the reaction opens useful synthetic routes to polycyclic compounds such as unsymmetrical anthracene, anthracenone, and anthraquinone derivatives.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent4p.en
dc.language.isoenen
dc.relation.ispartofseriesOrganic Lettersen
dc.rights© 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.orglett.5b01955].en
dc.subjectDRNTU::Science::Chemistryen
dc.titleOrtho-C–H Benzylation of Aryl Imines with Benzyl Phosphates under Cobalt–Pyphos Catalysisen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doihttp://dx.doi.org/10.1021/acs.orglett.5b01955en
dc.description.versionAccepted versionen
item.grantfulltextopen-
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