Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103784
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dc.contributor.authorChi, Robin Yongguien
dc.contributor.authorJin, Zhichaoen
dc.contributor.authorJiang, Keen
dc.contributor.authorFu, Zhenqianen
dc.contributor.authorTorres, Jaumeen
dc.contributor.authorZheng, Pengchengen
dc.contributor.authorYang, Songen
dc.contributor.authorSong, Bao-Anen
dc.date.accessioned2015-06-12T02:22:11Zen
dc.date.accessioned2019-12-06T21:20:11Z-
dc.date.available2015-06-12T02:22:11Zen
dc.date.available2019-12-06T21:20:11Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationJin, Z., Jiang, K., Fu, Z., Torres, J., Zheng, P., Yang, S., et al. (2015). Nucleophilic β-carbon activation of propionic acid as a 3-carbon synthon by carbene organocatalysis. Chemistry - a European journal, 21(26), 9360-9363.en
dc.identifier.issn0947-6539en
dc.identifier.urihttps://hdl.handle.net/10356/103784-
dc.description.abstractDirect β-carbon activation of propionic acid (C2H5CO2H) by carbene organocatalysis has been developed. This activation affords the smallest azolium homoenolate intermediate (without any substituent) as a 3-carbon nucleophile for enantioselective reactions. Propionic acid is an excellent raw material because it is cheap, stable, and safe. This approach provides a much better solution to azolium homoenolate synthesis than the previously established use of acrolein (enal without any substituent), which is expensive, unstable, and toxic.en
dc.language.isoenen
dc.relation.ispartofseriesChemistry - a European journalen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistry::Organic chemistryen
dc.titleNucleophilic β-carbon activation of propionic acid as a 3-carbon synthon by carbene organocatalysisen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Biological Sciencesen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/chem.201501481en
item.fulltextNo Fulltext-
item.grantfulltextnone-
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