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Title: β-functionalization of carboxylic anhydrides with β-alkyl substituents through carbene organocatalysis
Authors: Jin, Zhichao
Chen, Shaojin
Wang, Yuhuang
Zheng, Pengcheng
Yang, Song
Chi, Robin Yonggui
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Carbanions
DRNTU::Science::Chemistry::Physical chemistry::Catalysis
Issue Date: 2014
Source: Jin, Z., Chen, S., Wang, Y., Zheng, P., Yang, S., & Chi, R. Y. (2014). β-functionalization of carboxylic anhydrides with β-alkyl substituents through carbene organocatalysis. Angewandte chemie international edition, 53(49), 13506-13509.
Series/Report no.: Angewandte chemie international edition
Abstract: The first NHC-catalyzed functionalization of carboxylic anhydrides is described. In this reaction, the β carbon behaves as a nucleophilic carbon and undergoes asymmetric reactions with electrophiles. Anhydrides with challenging β-alkyl substituents work effectively.
ISSN: 1433-7851
DOI: 10.1002/anie.201408604
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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