Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/104155
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dc.contributor.authorZhang, Junminen
dc.contributor.authorXing, Chongen
dc.contributor.authorTiwari, Bhoopendraen
dc.contributor.authorChi, Robin Yongguien
dc.date.accessioned2014-05-26T01:23:58Zen
dc.date.accessioned2019-12-06T21:27:35Z-
dc.date.available2014-05-26T01:23:58Zen
dc.date.available2019-12-06T21:27:35Z-
dc.date.copyright2013en
dc.date.issued2013en
dc.identifier.citationZhang, J., Xing, C., Tiwari, B., & Chi, Y. R. (2013). Catalytic Activation of Carbohydrates as Formaldehyde Equivalents for Stetter Reaction with Enones. Journal of the American Chemical Society, 135(22), 8113–8116.en
dc.identifier.issn0002-7863en
dc.identifier.urihttps://hdl.handle.net/10356/104155-
dc.description.abstractWe disclose the first catalytic activation of carbohydrates as formaldehyde equivalents to generate acyl anions as one-carbon nucleophilic units for a Stetter reaction. The activation involves N-heterocyclic carbene (NHC)-catalyzed C–C bond cleavage of carbohydrates via a retro-benzoin-type process to generate the acyl anion intermediates. This Stetter reaction constitutes the first success in generating formal formaldehyde-derived acyl anions as one-carbon nucleophiles for non-self-benzoin processes. The renewable nature of carbohydrates, accessible from biomass, further highlights the practical potential of this fundamentally interesting catalytic activation.en
dc.language.isoenen
dc.relation.ispartofseriesJournal of the American Chemical Societyen
dc.rights© 2013 American Chemical Society.en
dc.subjectDRNTU::Science::Chemistryen
dc.titleCatalytic activation of carbohydrates as formaldehyde equivalents for Stetter reaction with enonesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1021/ja401511ren
dc.identifier.rims173634en
item.grantfulltextnone-
item.fulltextNo Fulltext-
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