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https://hdl.handle.net/10356/104155
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhang, Junmin | en |
dc.contributor.author | Xing, Chong | en |
dc.contributor.author | Tiwari, Bhoopendra | en |
dc.contributor.author | Chi, Robin Yonggui | en |
dc.date.accessioned | 2014-05-26T01:23:58Z | en |
dc.date.accessioned | 2019-12-06T21:27:35Z | - |
dc.date.available | 2014-05-26T01:23:58Z | en |
dc.date.available | 2019-12-06T21:27:35Z | - |
dc.date.copyright | 2013 | en |
dc.date.issued | 2013 | en |
dc.identifier.citation | Zhang, J., Xing, C., Tiwari, B., & Chi, Y. R. (2013). Catalytic Activation of Carbohydrates as Formaldehyde Equivalents for Stetter Reaction with Enones. Journal of the American Chemical Society, 135(22), 8113–8116. | en |
dc.identifier.issn | 0002-7863 | en |
dc.identifier.uri | https://hdl.handle.net/10356/104155 | - |
dc.description.abstract | We disclose the first catalytic activation of carbohydrates as formaldehyde equivalents to generate acyl anions as one-carbon nucleophilic units for a Stetter reaction. The activation involves N-heterocyclic carbene (NHC)-catalyzed C–C bond cleavage of carbohydrates via a retro-benzoin-type process to generate the acyl anion intermediates. This Stetter reaction constitutes the first success in generating formal formaldehyde-derived acyl anions as one-carbon nucleophiles for non-self-benzoin processes. The renewable nature of carbohydrates, accessible from biomass, further highlights the practical potential of this fundamentally interesting catalytic activation. | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Journal of the American Chemical Society | en |
dc.rights | © 2013 American Chemical Society. | en |
dc.subject | DRNTU::Science::Chemistry | en |
dc.title | Catalytic activation of carbohydrates as formaldehyde equivalents for Stetter reaction with enones | en |
dc.type | Journal Article | en |
dc.contributor.school | School of Physical and Mathematical Sciences | en |
dc.identifier.doi | 10.1021/ja401511r | en |
dc.identifier.rims | 173634 | en |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
Appears in Collections: | SPMS Journal Articles |
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