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https://hdl.handle.net/10356/104207| Title: | Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes | Authors: | Fang, Xinqiang Chen, Xingkuan Lv, Hui Chi, Robin Yonggui |
Keywords: | DRNTU::Science::Chemistry::Organic chemistry | Issue Date: | 2011 | Source: | Fang, X., Chen, X., Lv, H., & Chi, Y. R. (2011). Enantioselective Stetter Reactions of Enals and Modified Chalcones Catalyzed by N-Heterocyclic Carbenes. Angewandte Chemie International Edition, 50(49), 11782–11785. | Series/Report no.: | Angewandte chemie international edition | Abstract: | New trick for an old cat.: Triazolium-based N-heterocyclic carbenes (NHCs) catalyze the selective generation of acyl anion equivalents for the title reaction. The stereoelectronic properties of the enal-derived Breslow intermediates and the unique reactivity of the modified chalcones are crucial for the Stetter reactions to occur. EWG=electron- withdrawing group. | URI: | https://hdl.handle.net/10356/104207 http://hdl.handle.net/10220/19457 |
DOI: | 10.1002/anie.201105812 | Rights: | © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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