Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/104214
Title: Asymmetric access to the smallest enolate intermediate via organocatalytic activation of acetic ester
Authors: Chen, Shaojin
Hao, Lin
Zhang, Yuexia
Tiwari, Bhoopendra
Chi, Robin Yonggui
Keywords: DRNTU::Science::Chemistry::Organic chemistry
Issue Date: 2013
Source: Chen, S., Hao, L., Zhang, Y., Tiwari, B., & Chi, Y. R. (2013). Asymmetric Access to the Smallest Enolate Intermediate via Organocatalytic Activation of Acetic Ester. Organic Letters, 15(22), 5822–5825.
Series/Report no.: Organic letters
Abstract: An NHC-catalyzed activation of acetic esters to afford enolate intermediates is disclosed. The catalytically generated triazolium enolate intermediates serve as two-carbon nucleophiles that undergo highly enantioselective reactions with enones and α,β-unsaturated imines to give α-unsubstituted δ-lactones and lactams, respectively.
URI: https://hdl.handle.net/10356/104214
http://hdl.handle.net/10220/19450
ISSN: 1523-7060
DOI: 10.1021/ol402877n
Rights: © 2013 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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