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Title: Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review
Authors: Rui, Xianhong
Yan, Qingyu
Skyllas-Kazacos, Maria
Lim, Tuti Mariana
Keywords: DRNTU::Engineering::Materials::Energy materials
Issue Date: 2014
Source: Rui, X., Yan, Q., Skyllas-Kazacos, M., & Lim, T. M. (2014). Li3V2(PO4)3 cathode materials for lithium-ion batteries: A review. Journal of Power Sources, 258, 19-38.
Series/Report no.: Journal of power sources
Abstract: The principal challenges facing the development of lithium ion batteries (LIBs) for hybrid electric/plug-in-hybrid (HEV/PHEV) vehicles and for off-peak energy storage are cost, safety, cell energy density (voltage × capacity), rate of charge/discharge, and service life. There are exciting developments in new positive electrode (cathode) materials to replace the LiCoO2 for use in the LIBs over the past decade. Monoclinic Li3V2(PO4)3 (LVP) with promising electrochemical properties including excellent cycling stability, high theoretical capacity (197 mAh g-1), low synthetic cost, improved safety characteristic, and low environmental impact emerges as highly suitable candidate. In this review, we focus on research work related to the LVP and discuss its host structure, mechanism of lithium insertion/extraction, transport properties (i.e., electronic conductivity, and lithium diffusion), synthesis and electrochemical properties. We highlight some recent development of LVP, which shows superior cycling stability and high rate capability and give some vision for the future research of LVP based electrode.
ISSN: 0378-7753
DOI: 10.1016/j.jpowsour.2014.01.126
Rights: © 2014 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Power Sources, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at:
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:CEE Journal Articles
ERI@N Journal Articles
MSE Journal Articles

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