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Title: A carbone-stabilized two-coordinate phosphorus(III)-centered dication
Authors: Tay, Madelyn Qin Yi
Lu, Yunpeng
Ganguly, Rakesh
Vidović, Dragoslav
Issue Date: 2013
Source: Tay, M. Q. Y., Lu, Y., Ganguly, R., & Vidović, D. (2013). A Carbone-Stabilized Two-Coordinate Phosphorus(III)-Centered Dication. Angewandte Chemie International Edition, 52(11), 3132-3135.
Series/Report no.: Angewandte chemie international edition
Abstract: A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication.
ISSN: 1433-7851
DOI: 10.1002/anie.201209223
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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