Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/105291
Title: A carbone-stabilized two-coordinate phosphorus(III)-centered dication
Authors: Tay, Madelyn Qin Yi
Lu, Yunpeng
Ganguly, Rakesh
Vidović, Dragoslav
Issue Date: 2013
Source: Tay, M. Q. Y., Lu, Y., Ganguly, R., & Vidović, D. (2013). A Carbone-Stabilized Two-Coordinate Phosphorus(III)-Centered Dication. Angewandte Chemie International Edition, 52(11), 3132-3135.
Series/Report no.: Angewandte chemie international edition
Abstract: A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication.
URI: https://hdl.handle.net/10356/105291
http://hdl.handle.net/10220/16600
ISSN: 1433-7851
DOI: 10.1002/anie.201209223
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

SCOPUSTM   
Citations 10

43
Updated on Nov 28, 2022

Web of ScienceTM
Citations 10

45
Updated on Nov 29, 2022

Page view(s) 50

409
Updated on Dec 6, 2022

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.