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Title: Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile
Authors: Vidović, Dragoslav
Kong, Ling Bing
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Keywords: DRNTU::Science::Chemistry
Issue Date: 2014
Source: Kong, L., Li, Y., Ganguly, R., Vidovic, D., & Kinjo, R. (2014). Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile. Angewandte Chemie International Edition, 53(35), 9280-9283.
Series/Report no.: Angewandte Chemie international edition
Abstract: An isolable phenylborylene species supported by two oxazol-2-ylidene ligands was synthesized and structurally characterized. Computational studies revealed the presence of lone-pair electrons on the boron atom in this molecule; therefore, there are eight electrons around the three-coordinate boron center. The nucleophilic property was confirmed by the reactions with trifluoromethanesulfonic acid and [(thf)Cr(CO)5], which gave the corresponding conjugate acid and a chromium–borylene complex, respectively.
ISSN: 1433-7851
DOI: 10.1002/anie.201405201
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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