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https://hdl.handle.net/10356/105487| Title: | Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones | Authors: | Huang, Zhiyan Chen, Zuliang Lim, Li Hui Quang, Gia Chuong Phan Hirao, Hajime Zhou, Jianrong Steve |
Issue Date: | 2013 | Source: | Huang, Z., Chen, Z., Lim, L. H., Quang, G. C. P., Hirao, H., & Zhou, J. S. (2013). Weak arene C - H⋅⋅⋅O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones. Angewandte chemie international edition, 52(22), 5807-5812. | Series/Report no.: | Angewandte chemie international edition | Abstract: | Weak force in action: In the title reaction, the palladium catalyst (see figure, left) uses weak CH⋅⋅⋅O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH⋅⋅⋅O hydrogen bonding to guide stereoselection. | URI: | https://hdl.handle.net/10356/105487 http://hdl.handle.net/10220/16585 |
ISSN: | 1433-7851 | DOI: | 10.1002/anie.201300481 | Schools: | School of Physical and Mathematical Sciences | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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