Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/105516
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dc.contributor.authorDas, Mrinmoyen
dc.contributor.authorVu, Minh Duyen
dc.contributor.authorZhang, Qien
dc.contributor.authorLiu, Xue-Weien
dc.date.accessioned2019-03-14T06:15:44Zen
dc.date.accessioned2019-12-06T21:52:50Z-
dc.date.available2019-03-14T06:15:44Zen
dc.date.available2019-12-06T21:52:50Z-
dc.date.issued2019en
dc.identifier.citationDas, M., Vu, M. D., Zhang, Q., & Liu, X.-W. (2019). Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation . Chemical Science, 10(6), 1687-1691. doi:10.1039/C8SC04195Den
dc.identifier.issn2041-6520en
dc.identifier.urihttps://hdl.handle.net/10356/105516-
dc.description.abstractCarbyne, an interesting synthetic intermediate, has recently been generated from hypervalent iodine precursors via photoredox catalysis. Given the underexplored chemistry of carbyne, due to the paucity of carbyne sources, we are intrigued to discover a new source for this reactive species from classical reagents – phosphonium ylides. Our novel strategy employing phosphonium ylides in an olefin hydrocarbonation reaction features a facile approach for constructing carbon–carbon bonds through metal-free and benign reaction conditions. Moreover, the hydrocarbonation products were delivered in a highly regioselective manner.en
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent5 p.en
dc.language.isoenen
dc.relation.ispartofseriesChemical Scienceen
dc.rights© 2019 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en
dc.subjectPhosphonium Ylideen
dc.subjectPhotoredoxen
dc.subjectDRNTU::Science::Chemistryen
dc.titleMetal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1039/C8SC04195Den
dc.description.versionPublished versionen
item.grantfulltextopen-
item.fulltextWith Fulltext-
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