Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/105516
Title: Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation
Authors: Das, Mrinmoy
Vu, Minh Duy
Zhang, Qi
Liu, Xue-Wei
Keywords: Phosphonium Ylide
Photoredox
DRNTU::Science::Chemistry
Issue Date: 2019
Source: Das, M., Vu, M. D., Zhang, Q., & Liu, X.-W. (2019). Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation . Chemical Science, 10(6), 1687-1691. doi:10.1039/C8SC04195D
Series/Report no.: Chemical Science
Abstract: Carbyne, an interesting synthetic intermediate, has recently been generated from hypervalent iodine precursors via photoredox catalysis. Given the underexplored chemistry of carbyne, due to the paucity of carbyne sources, we are intrigued to discover a new source for this reactive species from classical reagents – phosphonium ylides. Our novel strategy employing phosphonium ylides in an olefin hydrocarbonation reaction features a facile approach for constructing carbon–carbon bonds through metal-free and benign reaction conditions. Moreover, the hydrocarbonation products were delivered in a highly regioselective manner.
URI: https://hdl.handle.net/10356/105516
http://hdl.handle.net/10220/47810
ISSN: 2041-6520
DOI: 10.1039/C8SC04195D
Rights: © 2019 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

SCOPUSTM   
Citations 20

7
Updated on Jul 16, 2020

PublonsTM
Citations 20

9
Updated on Mar 4, 2021

Page view(s)

169
Updated on May 23, 2022

Download(s) 50

57
Updated on May 23, 2022

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.