Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/106059
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dc.contributor.authorBose, Purnandhuen
dc.contributor.authorBai, Linyien
dc.contributor.authorGanguly, Rakheshen
dc.contributor.authorZou, Ruqiangen
dc.contributor.authorZhao, Yanlien
dc.date.accessioned2015-07-08T06:46:36Zen
dc.date.accessioned2019-12-06T22:03:52Z-
dc.date.available2015-07-08T06:46:36Zen
dc.date.available2019-12-06T22:03:52Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationBose, P., Bai, L., Ganguly, R., Zou, R., & Zhao, Y. (2015). Rational design and synthesis of a highly porous copper-based interpenetrated metal-organic framework for high CO2 and H2 adsorption. ChemPlusChem, in press.en
dc.identifier.issn2192-6506en
dc.identifier.urihttps://hdl.handle.net/10356/106059-
dc.description.abstractInterpenetrated metal–organic frameworks (MOFs) are often observed to show lower porosity than their non-interpenetrating analogues. It would be highly desirable if the interpenetrated MOFs could still provide high stability, high rigidity, and optimal pore size for applications. In this work, an asymmetrical tricarboxylate organic linker was rationally designed for the construction of a copper(II)-based microporous MOF with a twofold interpenetrated structure of Pt3O4 topology. In spite of having structural interpenetration, the activated MOF shows high porosity with a Brunauer–Emmett–Teller surface area of 2297 m2g−1, and high CO2 (15.7 wt % at 273 K and 1 bar) and H2 uptake (1.64 wt % at 77 K and 1 bar).en
dc.language.isoenen
dc.relation.ispartofseriesChemPlusChemen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistry::Organic chemistryen
dc.titleRational design and synthesis of a highly porous copper-based interpenetrated metal-organic framework for high CO2 and H2 adsorptionen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science & Engineeringen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/cplu.201500104en
item.grantfulltextnone-
item.fulltextNo Fulltext-
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