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Title: A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations
Authors: Liu, Zhizhou
Lee, Jazreen Hui Qi
Ganguly, Rakesh
Vidović, Dragoslav
Keywords: DRNTU::Science::Chemistry::Physical chemistry::Catalysis
Issue Date: 2015
Source: Liu, Z., Lee, J. H. Q., Ganguly, R., & Vidović, D. (2015). A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations. Chemistry - A European Journal, 21(32), 11344-11348.
Series/Report no.: Chemistry - A European Journal
Abstract: A catalytically active aluminum-based system for Diels–Alder transformations is reported. The system was generated by mixing a β-diketiminate-stabilized aluminum bistriflate compound with Na[BArCl4] (ArCl=3,5-Cl2C6H3). Solid-state analysis of the catalytic system reveals a unique structure incorporating a two-dimensional coordination polymer. According to the experimental results obtained from several Diels–Alder transformations, the aluminum-based system appears to be a more practical and more robust alternative to the recently reported compounds based on carbon and silicon cations.
ISSN: 0947-6539
DOI: 10.1002/chem.201502205
Rights: © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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