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Title: Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism
Authors: Gurnani, Chitra
Đorđević, Nemanja
Muthaiah, Senthilkumar
Dimić, Dušan
Ganguly, Rakesh
Petković, Milena
Vidović, Dragoslav
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Carbanions
Issue Date: 2015
Source: Gurnani, C., Đorđević, N., Muthaiah, S., Dimić, D., Ganguly, R., Petković, M., et al. (2015). Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism. Chemical communications, 51(53), 10762-10764.
Series/Report no.: Chemical communications
Abstract: The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P–N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism.
DOI: 10.1039/C5CC03194J
Rights: © 2015 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Communications, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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