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Title: Degenerative xanthate transfer to olefins under visible-light photocatalysis
Authors: Kaga, Atsushi
Wu, Xiangyang
Lim, Joel Yi Jie
Hayashi, Hirohito
Lu, Yunpeng
Yeow, Edwin Kok Lee
Chiba, Shunsuke
Keywords: Energy Transfer
Issue Date: 2018
Source: Kaga, A., Wu, X., Lim, J. Y. J., Hayashi, H., Lu, Y., Yeow, E. K. L., & Chiba, S. (2018). Degenerative xanthate transfer to olefins under visible-light photocatalysis. Beilstein Journal of Organic Chemistry, 14, 3047-3058. doi:10.3762/bjoc.14.283
Series/Report no.: Beilstein Journal of Organic Chemistry
Abstract: The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF3)ppy}2(dtbbpy)](PF6) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical chain mechanism, which is initiated through triplet-sensitization of xanthates by the long-lived triplet state of the iridium-based photocatalyst.
ISSN: 1860-5397
DOI: 10.3762/bjoc.14.283
Rights: © 2018 Kaga et al.; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License ( Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions:(
Fulltext Permission: open
Fulltext Availability: With Fulltext
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