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Title: Lithium-ion conducting electrolyte salts for lithium batteries
Authors: Aravindan, Vanchiappan
Gnanaraj, Joe
Madhavi, Srinivasan
Liu, Hua-Kun
Keywords: DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry
Issue Date: 2011
Source: Aravindan, V., Gnanaraj, J., Madhavi, S.,& Liu, H. K. (2011). Lithium-ion conducting electrolyte salts for lithium batteries. Chemistry - a European journal, 17(51), 14326-14346.
Series/Report no.: Chemistry - a European journal
Abstract: This paper presents an overview of the various types of lithium salts used to conduct Li+ ions in electrolyte solutions for lithium rechargeable batteries. More emphasis is paid towards lithium salts and their ionic conductivity in conventional solutions, solid–electrolyte interface (SEI) formation towards carbonaceous anodes and the effect of anions on the aluminium current collector. The physicochemical and functional parameters relevant to electrochemical properties, that is, electrochemical stabilities, are also presented. The new types of lithium salts, such as the bis(oxalato)borate (LiBOB), oxalyldifluoroborate (LiODFB) and fluoroalkylphosphate (LiFAP), are described in detail with their appropriate synthesis procedures, possible decomposition mechanism for SEI formation and prospect of using them in future generation lithium-ion batteries. Finally, the state-of-the-art of the system is given and some interesting strategies for the future developments are illustrated.
ISSN: 0947-6539
DOI: 10.1002/chem.201101486
Rights: © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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