Please use this identifier to cite or link to this item:
|Title:||Synthesis and characterization of biphenyl-based lithium solvated electron solutions||Authors:||Grimsdale, Andrew C.
Tan, Kim Seng
|Keywords:||DRNTU::Engineering::Materials::Organic/Polymerelectronics||Issue Date:||2012||Source:||Tan, K. S., Grimsdale, A. C., & Yazami, R. (2012). Synthesis and characterization of biphenyl-based lithium solvated electron solutions. The Journal of Physical Chemistry B, 116(30), 9056-9060.||Series/Report no.:||The journal of physical chemistry B||Abstract:||We report on the electric conductivity measurements and FTIR studies carried out on lithium solvated electron solutions (Li-SES) using biphenyl as the electron receptor and tetrahydrofuran (THF) as the solvent. Conductivity measurements carried out on samples with varying compositions of lithium, biphenyl (β), and THF reveal the highest conductivity of 12.0 mS/cm is achieved with the solution composition Li1.0β(THF)8.2 and a metallic behavior. Characteristic fingerprint peaks attributed to the solvated electron solution appear in the FTIR spectra. Also, from the FTIR spectra, we propose a reaction mechanism of lithium reaction with biphenyl in THF in that Li1β(THF)n1 (1 Li atom pairing with 1 biphenyl molecule) is formed first followed by Li2β(THF)n1 (2 Li atoms pairing with 1 biphenyl molecule). A better understanding of the physical properties of the Li-SES is a prerequisite in view of their optimal applications as liquid anodes in lithium batteries.||URI:||https://hdl.handle.net/10356/106664
|DOI:||10.1021/jp302160a||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||ERI@N Journal Articles|
MSE Journal Articles
Updated on Nov 21, 2022
Web of ScienceTM
Updated on Nov 26, 2022
Page view(s) 20661
Updated on Nov 28, 2022
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.