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Title: Palladium-catalyzed stereoselective C-glycosylation of glycals with sodium arylsulfinates
Authors: Ma, Jimei
Xiang, Shaohua
Jiang, Hong
Liu, Xue-Wei
Keywords: DRNTU::Science::Chemistry::Organic chemistry
Issue Date: 2015
Source: Ma, J., Xiang, S., Jiang, H., & Liu, X.-W. (2015). Palladium-catalyzed stereoselective C-glycosylation of glycals with sodium arylsulfinates. European journal of organic chemistry, 2015(5), 949-952.
Series/Report no.: European journal of organic chemistry
Abstract: An efficient glycosylation method to synthesize 2-deoxy-C-aryl glycosides was developed. This C-glycosylation strategy is based on a palladium-catalyzed desulfitative Ferrier-type coupling reaction of glycals and sodium arylsulfinates. A series of C-aryl glycosides were obtained in moderate to good yields with exclusive regio- and stereoselectivities. The anomeric selectivity was found to depend on the configuration of the C3 substituent of the glycals.
ISSN: 1434-193X
DOI: 10.1002/ejoc.201403550
Rights: © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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