Please use this identifier to cite or link to this item:
Title: Covalent organic frameworks formed with two types of covalent bonds based on orthogonal reactions
Authors: Zeng, Yongfei
Zou, Ruyi
Luo, Zhong
Zhang, Huacheng
Yao, Xin
Ma, Xing
Zou, Ruqiang
Zhao, Yanli
Keywords: DRNTU::Science::Chemistry::Organic chemistry
Issue Date: 2015
Source: Zeng, Y., Zou, R., Luo, Z., Zhang, H., Yao, X., Ma, X., et al. (2015). Covalent organic frameworks formed with two types of covalent bonds based on orthogonal reactions. Journal of the American chemical society, 137(3), 1020-1023.
Series/Report no.: Journal of the American chemical society
Abstract: Covalent organic frameworks (COFs) are excellent candidates for various applications. So far, successful methods for the constructions of COFs have been limited to a few condensation reactions based on only one type of covalent bond formation. Thus, the exploration of a new judicious synthetic strategy is a crucial and emergent task for the development of this promising class of porous materials. Here, we report a new orthogonal reaction strategy to construct COFs by reversible formations of two types of covalent bonds. The obtained COFs consisting of multiple components show high surface area and high H2 adsorption capacity. The strategy is a general protocol applicable to construct not only binary COFs but also more complicated systems in which employing regular synthetic methods did not work.
ISSN: 1520-5126
DOI: 10.1021/ja510926w
Schools: School of Physical and Mathematical Sciences 
Rights: ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

Citations 1

Updated on Feb 18, 2024

Web of ScienceTM
Citations 1

Updated on Oct 26, 2023

Page view(s) 50

Updated on Feb 26, 2024

Download(s) 20

Updated on Feb 26, 2024

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.