Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/107206
Title: Covalent organic frameworks formed with two types of covalent bonds based on orthogonal reactions
Authors: Zeng, Yongfei
Zou, Ruyi
Luo, Zhong
Zhang, Huacheng
Yao, Xin
Ma, Xing
Zou, Ruqiang
Zhao, Yanli
Keywords: DRNTU::Science::Chemistry::Organic chemistry
Issue Date: 2015
Source: Zeng, Y., Zou, R., Luo, Z., Zhang, H., Yao, X., Ma, X., et al. (2015). Covalent organic frameworks formed with two types of covalent bonds based on orthogonal reactions. Journal of the American chemical society, 137(3), 1020-1023.
Series/Report no.: Journal of the American chemical society
Abstract: Covalent organic frameworks (COFs) are excellent candidates for various applications. So far, successful methods for the constructions of COFs have been limited to a few condensation reactions based on only one type of covalent bond formation. Thus, the exploration of a new judicious synthetic strategy is a crucial and emergent task for the development of this promising class of porous materials. Here, we report a new orthogonal reaction strategy to construct COFs by reversible formations of two types of covalent bonds. The obtained COFs consisting of multiple components show high surface area and high H2 adsorption capacity. The strategy is a general protocol applicable to construct not only binary COFs but also more complicated systems in which employing regular synthetic methods did not work.
URI: https://hdl.handle.net/10356/107206
http://hdl.handle.net/10220/25349
ISSN: 1520-5126
DOI: 10.1021/ja510926w
Rights: ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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