Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/107341
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dc.contributor.authorPoh, Hwee Lingen
dc.contributor.authorSofer, Zdeněken
dc.contributor.authorŠimek, Petren
dc.contributor.authorTomandl, Ivoen
dc.contributor.authorPumera, Martinen
dc.date.accessioned2015-05-20T02:59:03Zen
dc.date.accessioned2019-12-06T22:29:07Z-
dc.date.available2015-05-20T02:59:03Zen
dc.date.available2019-12-06T22:29:07Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationPoh, H. L., Sofer, Z., Šimek, P., Tomandl, I., & Pumera, M. (2015). Hydroboration of graphene oxide : towards stoichiometric graphol and hydoroxygraphane. Chemistry - a European journal, 21(22), 8130-8136.en
dc.identifier.issn0947-6539en
dc.identifier.urihttps://hdl.handle.net/10356/107341-
dc.description.abstractCovalently functionalized graphene materials with well-defined stoichiometric composition are of a very high importance in the research of 2D carbon material family due to their well-defined properties. Unfortunately, most of the contemporary graphene-functionalized materials do not have this kind of defined composition and, usually, the amount of heteroatoms bonded to graphene framework is in the range of 1–10 at. %. Herein, we show that by a well-established hydroboration reaction chain, which introduces ——BH2 groups into the graphene oxide structure, followed by H2O2 or CF3COOH treatment as source of ——OH or ——H, we can obtain highly hydroxylated compounds of precisely defined composition with a general formula (C1O0.78H0.75)n, which we named graphol and highly hydroxylated graphane (C1(OH)0.51H0.14)n, respectively. These highly functionalized materials with an accurately defined composition are highly important for the field of graphene derivatives. The enhanced electrochemical performance towards important biomarkers as well as hydrogen evolution reaction is demonstrated.en
dc.language.isoenen
dc.relation.ispartofseriesChemistry - a European journalen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistry::Physical chemistry::Electrochemistryen
dc.titleHydroboration of graphene oxide : towards stoichiometric graphol and hydoroxygraphaneen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/chem.201406168en
item.fulltextNo Fulltext-
item.grantfulltextnone-
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