Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/136693
Title: Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis
Authors: Barik, Chandan Kr
Ganguly, Rakesh
Li, Yongxin
Leong, Weng kee
Keywords: Science::Chemistry
Science::Chemistry::Inorganic chemistry
Issue Date: 2018
Source: Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis. European Journal of Inorganic Chemistry, 2018(46), 4982-4986. doi:10.1002/ejic.201801012
Journal: European Journal of Inorganic Chemistry
Abstract: The ruthenacyclic carbamoyl complexes [RuX{2-NHC(O)C5H3NR}(CO)2(NCMe)] (R = H and Me; X = Br and SC6H3-o,o-Me2) are excellent catalysts for the hydrolysis of organosilanes, particularly towards primary silanes, generating hydrogen under ambient conditions within seconds. These complexes are structural mimics of the [Fe]-hydrogenase active site and like the natural enzyme, a labile ligand at the sixth coordination site is essential to the catalytic activity.
URI: https://hdl.handle.net/10356/136693
ISSN: 1434-1948
DOI: 10.1002/ejic.201801012
Rights: This is the peer reviewed version of the following article: Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis. European Journal of Inorganic Chemistry, 2018(46), 4982-4986. doi:10.1002/ejic.201801012, which has been published in final form at 10.1002/ejic.201801012. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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