Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/136693
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dc.contributor.authorBarik, Chandan Kren_US
dc.contributor.authorGanguly, Rakeshen_US
dc.contributor.authorLi, Yongxinen_US
dc.contributor.authorLeong, Weng Keeen_US
dc.date.accessioned2020-01-10T06:37:06Z-
dc.date.available2020-01-10T06:37:06Z-
dc.date.issued2018-
dc.identifier.citationBarik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis. European Journal of Inorganic Chemistry, 2018(46), 4982-4986. doi:10.1002/ejic.201801012en_US
dc.identifier.issn1434-1948en_US
dc.identifier.urihttps://hdl.handle.net/10356/136693-
dc.description.abstractThe ruthenacyclic carbamoyl complexes [RuX{2-NHC(O)C5H3NR}(CO)2(NCMe)] (R = H and Me; X = Br and SC6H3-o,o-Me2) are excellent catalysts for the hydrolysis of organosilanes, particularly towards primary silanes, generating hydrogen under ambient conditions within seconds. These complexes are structural mimics of the [Fe]-hydrogenase active site and like the natural enzyme, a labile ligand at the sixth coordination site is essential to the catalytic activity.en_US
dc.description.sponsorshipASTAR (Agency for Sci., Tech. and Research, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.rightsThis is the peer reviewed version of the following article: Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis. European Journal of Inorganic Chemistry, 2018(46), 4982-4986. doi:10.1002/ejic.201801012, which has been published in final form at 10.1002/ejic.201801012. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.subjectScience::Chemistryen_US
dc.subjectScience::Chemistry::Inorganic chemistryen_US
dc.titleRuthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysisen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1002/ejic.201801012-
dc.description.versionAccepted versionen_US
dc.identifier.scopus2-s2.0-85057577457-
dc.identifier.issue46en_US
dc.identifier.volume2018en_US
dc.identifier.spage4982en_US
dc.identifier.epage4986en_US
dc.subject.keywordsOrganosilane Hydrolysisen_US
dc.subject.keywordsRuthenacyclic Carbamoyl Complexen_US
item.grantfulltextopen-
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